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Henry Rzepa's Blog

Henry Rzepa's Blog
Chemistry with a twist
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Interesting ChemistryAromatisation Stabilization EnergyChemical PolarityChemical PropertiesChemistryCiencias QuímicasInglés
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In several posts a year or so ago I considered various suggestions for the most polar neutral molecules, as measured by the dipole moment. A record had been claimed for a synthesized molecule of ~14.1±0.7D. I pushed this to a calculated 21.7D for an admittedly hypothetical and unsynthesized molecule.

Interesting ChemistryCity: LondonEnvironmentEnvironmental IssuesEnvironmental ToxicologyCiencias QuímicasInglés
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Around the time of the 2012 olympic games, the main site for which was Stratford in east London, I heard a fascinating talk about the “remediation” of the site from the pollution caused by its industrial chemical heritage. Here I visit another, arguably much more famous and indeed older industrial site.

HypervalencyCChemical BondingChemistryFree EnergyCiencias QuímicasInglés
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Another post inspired by a comment on an earlier one; I had been discussing compounds of the type I.In (n=4,6) as possible candidates for hypervalency. The comment suggests the below as a similar analogue, deriving from observations made in 1989.