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Henry Rzepa's Blog

Henry Rzepa's Blog
Chemistry with a twist
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Interesting ChemistryAromatisation Stabilization EnergyChemical PolarityChemical PropertiesChemistryCiencias QuímicasInglés
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In several posts a year or so ago I considered various suggestions for the most polar neutral molecules, as measured by the dipole moment. A record had been claimed for a synthesized molecule of ~14.1±0.7D. I pushed this to a calculated 21.7D for an admittedly hypothetical and unsynthesized molecule.

Interesting ChemistryCity: LondonEnvironmentEnvironmental IssuesEnvironmental ToxicologyCiencias QuímicasInglés
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Around the time of the 2012 olympic games, the main site for which was Stratford in east London, I heard a fascinating talk about the “remediation” of the site from the pollution caused by its industrial chemical heritage. Here I visit another, arguably much more famous and indeed older industrial site.

HypervalencyCChemical BondingChemistryFree EnergyCiencias QuímicasInglés
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Another post inspired by a comment on an earlier one; I had been discussing compounds of the type I.In (n=4,6) as possible candidates for hypervalency. The comment suggests the below as a similar analogue, deriving from observations made in 1989.

Interesting ChemistryCity: LondonCountry: United KingdomRoyal Horticultural SocietyWildflowerCiencias QuímicasInglés
Publicado

Last year, I showed photos of wildflower meadows in west London close to where we live, evolving as the seasons changed. Today we hear the announcement that London itself is set be declared the world’s first National Park City in 2019.